Metal nitrosyl chemistry: Interesting oxidation and nitrosylation of a metal-bound ligand framework in a diamido-bis(phosphine) ruthenium(II) complex
نویسندگان
چکیده
منابع مشابه
Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes
Manganese metal-organic framework (Mn-MOF) containing Mn2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, e...
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249 The compounds (CS(CH3h)Co(NO)X (X = CI, Br, I) have been prepared by reaction of [(CS(CH3)s)Coh(p.-NOh with the appropriate dihalogen X 2• Either by spontaneous decomposition or by addition of half an equivalent of [(CS(CH3)s)CoClh(p.-Clh, the chloro derivative forms the binuclear complex [(CS(CH3)s)CoClh(p.-NO)(p.-CI), the crystal structure of which indicates the presence of a nitrosyl bri...
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Metal-organic frameworks (MOFs) have potential applications as energy absorbing materials for shock wave energy mitigation due to their nanoporosity. Here we have examined km/s laser-driven flyer plate impacts on a prototypical MOF, ZIF-8. We observed particle fragmentation and morphological changes in microcrystals of ZIF-8 at lower shock pressures (≈2.5 GPa), and amorphization and structural ...
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By coupling of Fe2O3@SiO2 particles with metal organic Framework (MOF) the magnetic MOF structure was fabricated. Precipitation and hydrothermal methods were applied for synthesis of core and MOF. Silver nanoparticles were deposited on nickel based metal organic framework surface and magnetic Fe2O3@SiO2@MOF@Ag was obtained. Because of strong coupling between silver nanoparticles and metal organ...
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ساخت الکترودهاِی اصلاح شده ِیکِی از چالشهاِی همِیشگِی در دانش شیمِی بوِیژه شیمِی تجزیه مِی باشد ،که با در نظر گرفتن سادگِی ساخت، کاربردی بودن و ارزان بودن روش مِی توان به باارزش بودن چنِین سنسورهاِی پِی برد.آنچه که در ادامه آورده شده به ساخت و کاربرد الکترودهاِی اصلاح شده با استفاده از نانو ذرات در اندازه گِیرِی ولتامترِی آهن وکادمِیم اشاره دارد. کار اول اختصاص دارد به ساخت الکترود خمِیر کربن اصلاح شده با لِیگاند داِ...
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ژورنال
عنوان ژورنال: Inorganica Chimica Acta
سال: 2016
ISSN: 0020-1693
DOI: 10.1016/j.ica.2016.06.001